Halogen-Dependent Diversity and Weak Interactions in the Heterometallic Ni/Cd Complex Solids: Structural and Theoretical Investigation.

ABSTRACT: Three novel heterometallic Ni/Cd coordination compounds [Ni(en)₃][CdCl₄]∙3dmso (1), [Ni(en)₂(dmf)₂][CdBr₄] (2), and [Ni(en)₃]₂[CdI₄](I)₂ (3) have been synthesized through the self-assembly process in a one-pot reaction of cadmium oxide, nickel salt (or nickel powder), NH₄X (X = Cl, Br, I), and ethylenediamine in non-aqueous solvents dmso (for 1) or dmf (for 2 and 3). Formation of the one- (1) or three-dimensional (2 and 3) hydrogen-bonded frameworks has been observed depending on the nature of the [CdX₄]^2- counter-anion, as well as on the nature of the solvent. The electronic structures of [Ni(en)<

SUBMITTER: Nesterova OV 

PROVIDER: S-EPMC10674445 | biostudies-literature | 2023 Nov

REPOSITORIES: biostudies-literature