Synthesis of aromatic polynitroso compounds: Towards functional azodioxy-linked porous polymers.

ABSTRACT: The polymerization property of aromatic polynitroso compounds could be used to create azodioxy porous networks with possible application for the adsorption of CO₂, the main greenhouse gas. Herein, we report the synthesis and characterization of new aromatic polynitroso compounds, with para-nitroso groups attached to the triphenylbenzene, triphenylpyridine, triphenyltriazine and triphenylamine moiety. The synthesis of the pyridine-based trinitroso compound was performed by reduction of the corresponding trinitro derivative to N-arylhydroxylamine followed by oxidation to the trinitroso product. For the synthesis of the benzene- and triazine-based trinitroso compounds, a novel synthetic strategy was implemented, which included cyclotrimerization of the 4-nitrosoacetop

SUBMITTER: Cindro N 

PROVIDER: S-EPMC10685250 | biostudies-literature | 2023 Nov

REPOSITORIES: biostudies-literature