Palladium complex supported on the surface of magnetic Fe₃O₄ nanoparticles: an ecofriendly catalyst for carbonylative Suzuki-coupling reactions.

ABSTRACT: Diaryl ketone derivatives include well-known compounds with important physiological and biological properties. In order to prepare diaryl ketone derivatives, we constructed a pallidum (0) complex immobilized on Fe₃O₄ nanoparticles modified with aminobenzoic acid and phenanthroline [Fe₃O₄@ABA/Phen-DCA-Pd(0)], and evaluated its catalytic performance for carbonylative Suzuki-coupling reactions of aryl iodides with aryl boronic acid in the presence of Mo(CO)₆ as the CO source under mild conditions. FT-IR, SEM, TEM, EDX, VSM, TGA, XRD, ICP-OES and Elemental mapping techniques were employed to identify the structure of the Fe₃O₄@ABA/Phen-DCA-Pd(0) nanocatalyst. Different derivatives of aryl iodides and aryl boronic acid

SUBMITTER: Jiang S 

PROVIDER: S-EPMC10690082 | biostudies-literature | 2023 Nov

REPOSITORIES: biostudies-literature