Intramolecular Hydrogen Bond Improved Durability and Kinetics for Zinc-Organic Batteries.

ABSTRACT: Organic compounds have the advantages of green sustainability and high designability, but their high solubility leads to poor durability of zinc-organic batteries. Herein, a high-performance quinone-based polymer (H-PNADBQ) material is designed by introducing an intramolecular hydrogen bonding (HB) strategy. The intramolecular HB (C=O⋯N-H) is formed in the reaction of 1,4-benzoquinone and 1,5-naphthalene diamine, which efficiently reduces the H-PNADBQ solubility and enhances its charge transfer in theory. In situ ultraviolet-visible analysis further reveals the insolubility of H-PNADBQ during the electrochemical cycles, enabling high durability at different current densities. Specifically, the H-PNADBQ electrode with high loading (10 mg cm^-2) performs a long cycling life at 125 

SUBMITTER: Sun T 

PROVIDER: S-EPMC10709292 | biostudies-literature | 2023 Dec

REPOSITORIES: biostudies-literature