Crystal-facet-dependent surface transformation dictates the oxygen evolution reaction activity in lanthanum nickelate.

ABSTRACT: Electrocatalysts are the cornerstone in the transition to sustainable energy technologies and chemical processes. Surface transformations under operation conditions dictate the activity and stability. However, the dependence of the surface structure and transformation on the exposed crystallographic facet remains elusive, impeding rational catalyst design. We investigate the (001), (110) and (111) facets of a LaNiO_3-δ electrocatalyst for water oxidation using electrochemical measurements, X-ray spectroscopy, and density functional theory calculations with a Hubbard U term. We reveal that the (111) overpotential is ≈ 30-60 mV lower than for the other facets. While a surface transformation into oxyhydroxide-like NiOO(H) may occur for all three orientations, it is more pronounced f

SUBMITTER: Fungerlings A 

PROVIDER: S-EPMC10719283 | biostudies-literature | 2023 Dec

REPOSITORIES: biostudies-literature