Never-Ending Story: New Cyclodextrin-Based Metal-Organic Framework Crystal Structures Obtained Using Different Crystallization Methods.

ABSTRACT: Six novel cyclodextrin (CD)-based metal-organic frameworks (MOFs) were synthesized using distinct crystallization methodologies. A modified vapor diffusion method is introduced for the first time, termed fast crystallization, which enables the rapid solid-state formation of MOF compounds. This innovative method yielded four of the newly synthesized MOFs. The crystal structures of five obtained frameworks were structurally characterized through single-crystal X-ray diffraction, while one, compound 5 (γ-CD-K-5), was additionally characterized as a bulk powder. Structural analysis revealed that two of the newly obtained MOFs, namely, compound 2 (α-CD-K-2) and compound 3 (α-CD-Rb-3), exhibited isostructural characteristics, forming a three-dimensional (3D) framework. Compo

SUBMITTER: Krukle-Berzina K 

PROVIDER: S-EPMC10733991 | biostudies-literature | 2023 Dec

REPOSITORIES: biostudies-literature