A New 3D Iodoargentate Hybrid: Structure, Optical/Photoelectric Performance and Theoretical Research.

ABSTRACT: The explorations of new three-dimensional (3D) microporous metal halides, especially the iodoargentate-based hybrids, and understanding of their structure-activity relationships are still quite essential but full of great challenges. Herein, with the aromatic 4,4'-dpa (4,4'-dpa = 4,4'-dipyridylamine) ligands as the structural directing agents, we solvothermal synthesized and structurally characterized a novel member of microporous iodoargentate family, namely [H₂-4,4'-dpa]Ag₆I₈ (1). Compound 1 possesses a unique and complicated 3D [Ag₆I₈]_n^2n- anionic architecture that was built up from the unusual hexameric [Ag₆I₁₃] secondary building units (SBUs). Research on opti

SUBMITTER: Li J 

PROVIDER: S-EPMC10745466 | biostudies-literature | 2023 Dec

REPOSITORIES: biostudies-literature