Synthesis and Structures of Lead(II) Complexes with Substituted Derivatives of the Closo-Decaborate Anion with a Pendant N₃ Group.

ABSTRACT: In this work, we studied lead(II) and cobalt(II) complexation of derivatives [2-B₁₀H₉O(CH₂)₂O(CH₂)₂N₃]^2- and [2-B₁₀H₉O(CH₂)₅N₃]^2- of the closo-decaborate anion containing pendant azido groups in the presence of 1,10-phenanthroline and 2,2'-bipyridyl. Mononuclear [PbL₂{An}] and binuclear [Pb₂L₄(NO₃)₂{An}] lead complexes (where {An} is the N₃-substituted boron cluster) were isolated and studied by IR spectroscopy and elemental analysis. The mononuclear lead(II) complex [Pb(phen)₂[B₁₀H₉O(CH₂)₂O(CH₂)₂

SUBMITTER: Matveev EY 

PROVIDER: S-EPMC10746007 | biostudies-literature | 2023 Dec

REPOSITORIES: biostudies-literature