Initial-site characterization of hydrogen migration following strong-field double-ionization of ethanol.

ABSTRACT: An essential problem in photochemistry is understanding the coupling of electronic and nuclear dynamics in molecules, which manifests in processes such as hydrogen migration. Measurements of hydrogen migration in molecules that have more than two equivalent hydrogen sites, however, produce data that is difficult to compare with calculations because the initial hydrogen site is unknown. We demonstrate that coincidence ion-imaging measurements of a few deuterium-tagged isotopologues of ethanol can determine the contribution of each initial-site composition to hydrogen-rich fragments following strong-field double ionization. These site-specific probabilities produce benchmarks for calculations and answer outstanding questions about photofragmentation of ethanol dications; e.g., establishing t

SUBMITTER: Severt T 

PROVIDER: S-EPMC10761976 | biostudies-literature | 2024 Jan

REPOSITORIES: biostudies-literature