Magnetic-biased chiral molecules enabling highly oriented photovoltaic perovskites.

ABSTRACT: The interaction between sites A, B and X with passivation molecules is restricted when the conventional passivation strategy is applied in perovskite (ABX₃) photovoltaics. Fortunately, the revolving A-site presents an opportunity to strengthen this interaction by utilizing an external field. Herein, we propose a novel approach to achieving an ordered magnetic dipole moment, which is regulated by a magnetic field via the coupling effect between the chiral passivation molecule and the A-site (formamidine ion) in perovskites. This strategy can increase the molecular interaction energy by approximately four times and ensure a well-ordered molecular arrangement. The quality of the deposited perovskite film is significantly optimized with inhibited nonradiative recombination. It manag

SUBMITTER: Chen J 

PROVIDER: S-EPMC10776365 | biostudies-literature | 2024 Feb

REPOSITORIES: biostudies-literature