Acid selenites as new selenium precursor for CdSe quantum dot synthesis.
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ABSTRACT: Chemical precursors for nanomaterials synthesis have become essential to tune particle size, composition, morphology, and unique properties. New inexpensive precursors investigation that precisely controls these characteristics is highly relevant. We studied new Se precursors, the acid selenites (R-O-SeOOH), to synthesize CdSe quantum dots (QDs). They were produced at room temperature by the Image 1 reaction with alcohols having different alkyl chains and were characterized by 1H NMR confirming their structures. This unprecedented precursor generates high-quality CdSe nanocrystals with narrow size distribution in the zinc-blend structure showing controlled optical properties. Advanced characterization detailed the CdSe structure showing stacking fault defects and its dependence
SUBMITTER: Souza Junior JB
PROVIDER: S-EPMC10777003 | biostudies-literature | 2024 Jan
REPOSITORIES: biostudies-literature
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