Volatile Memristive Devices with Analog Resistance Switching Based on Self-Assembled Squaraine Microtubes as Synaptic Emulators.

ABSTRACT: In this work, the discovery of volatile memristive devices that exhibit analog resistive switching (RS) and synaptic emulation based on squaraine materials is presented. Specifically, organic microtubes (MTs) based on 2,4-bis[(4-(N,N-diisobutyl)-2-6-hydroxyphenyl]squaraine (SQ) are prepared by evaporation-induced self-assembly (EISA). The MTs are ca. 2 μm in diameter (aspect ratio: 10-130). While powder X-ray diffraction data for MTs identify monoclinic and orthorhombic polymorphs, optical data report the monoclinic phase with energetic disorder. By favorable energetic alignment of the Au work function with the SQ HOMO energy, unipolar (hole-only) symmetric metal-insulator-metal devices are formed by EISA of MT meshes on interdigitated electrodes. The DC I-V characteri

SUBMITTER: Griffin K 

PROVIDER: S-EPMC10797587 | biostudies-literature | 2024 Jan

REPOSITORIES: biostudies-literature