Hydrogen-bonded organic frameworks in solution enables continuous and high-crystalline membranes.

ABSTRACT: Hydrogen-Bonded organic frameworks (HOFs) are a type of emerging porous materials. At present, little research has been conducted on their solution state. This work demonstrates that HOFs fragment into small particles while maintaining their original assemblies upon dispersing in solvents, as confirmed by Cryo-electron microscopy coupled with 3D electron diffraction technology. 1D and 2D-Nuclear Magnetic Resonance (NMR) and zeta potential analyses indicate the HOF-based colloid solution and the isolated molecular solution have significant differences in intermolecular interactions and aggregation behavior. Such unique solution processibility allows for fabricating diverse continuous HOF membranes with high crystallinity and porosity through solution-casting approach on various substrates.

SUBMITTER: Yin Q 

PROVIDER: S-EPMC10799873 | biostudies-literature | 2024 Jan

REPOSITORIES: biostudies-literature