Coordination chemistry effects of the space-demanding solvent molecule N,N'-dimethylpropyleneurea.

ABSTRACT: Crystallographic investigations of eight homoleptic N,N'-dimethylpropyleneurea (dmpu) coordinated metal ions in the solid state, [Mg(dmpu)₅]I₂ (1), [Ca(dmpu)₆]I₂ (2), [Ca(dmpu)₆](ClO₄)₂ (3), [Ca(dmpu)₆](CF₃SO₃)₂ (4), [Sr(dmpu)₆](CF₃SO₃)₂ (5), [Ba(dmpu)₆](CF₃SO₃)₂ (6), [Sc(dmpu)₆]I₃ (7), and [Pr(dmpu)₆]I(I₃)₂ (8), and the complex [CoBr₂(dmpu)₂] (9) as well as the structures of the dmpu coordinated calcium, strontium, barium, scandium(III) and cobalt(II) ions and the cobalt(II) bromide complex in

SUBMITTER: Lundberg D 

PROVIDER: S-EPMC10805073 | biostudies-literature | 2024 Jan

REPOSITORIES: biostudies-literature