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Water-promoted selective photocatalytic methane oxidation for methanol production.


ABSTRACT: Converting relatively inert methane into active chemical fuels such as methanol with high selectivity through an energy-saving strategy has remained a grand challenge. Photocatalytic technology consuming solar energy is an appealing alternative for methane reforming. However, the low efficiency and the undesirable formation of low-value products, such as carbon dioxide and ethane, limit the commercial application of photocatalytic technology. Herein, we find a facile and practical water-promoted pathway for photocatalytic methane reforming into methanol, enabling methanol production from methane and oxygen with a high selectivity (>93%) and production rate (21.4 μmol cm-2 h-1 or 45.5 mmol g-1 h-1) on metallic Ag nanoparticle-loaded InGaN nanowire

SUBMITTER: Zhou P 

PROVIDER: S-EPMC10806830 | biostudies-literature | 2024 Jan

REPOSITORIES: biostudies-literature