From Simple Palladium(II) Monomers to 2D Heterometallic Sodium-Palladium(II) Coordination Networks with 2-Halonicotinates.

ABSTRACT: The 2D heterometallic sodium-palladium(II) coordination polymers with 2-halonicotinates [2-chloropyridine-3-carboxylate (2-chloronicotinate), 2-Clnic^- and 2-bromopyridine-3-carboxylate (2-bromonicotinate), 2-Brnic^-], {[Na₂(H₂O)₂(μ-H₂O)₄PdCl₂(μ-2-Clnic-N:O')₂]}_n (1), and {[Na₂(H₂O)₂(μ-H₂O)₄PdBr₂(μ-2-Brnic-N:O')₂]·2H₂O}_n (2) were prepared in aqueous solutions under the presence of NaHCO₃, while palladium(II) monomers with the neutral 2-chloronicotinic and 2-bromonicotinic acid ligands, [PdCl₂(2-ClnicH-N)₂]

SUBMITTER: Kodrin I 

PROVIDER: S-EPMC10809674 | biostudies-literature | 2024 Jan

REPOSITORIES: biostudies-literature