Chemical Information Processing by a Responsive Chemical System.
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ABSTRACT: Nature has an extraordinary capacity to precisely regulate the chemical reactivity in a highly complex mixture of molecules that is present in the cell. External stimuli lead to transient up- and downregulation of chemical reactions and provide a means for a cell to process information arriving from the environment. The development of synthetic chemical systems with life-like properties requires strategies that allow likewise control over chemical reactivity in a complex environment. Here, we show a synthetic system that mimics the initial steps that take place when a natural signal transduction pathway is activated. Monophosphate nucleosides act as chemical triggers for the self-assembly of nanoreactors that upregulate chemical reactions between reagents present at low micromolar concentr
SUBMITTER: Gabrielli L
PROVIDER: S-EPMC10811666 | biostudies-literature | 2024 Jan
REPOSITORIES: biostudies-literature
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