Cu(II) Coordination Polymers Containing Mixed Ligands with Different Flexibilities: Structural Diversity and Iodine Adsorption.

ABSTRACT: Reactions of N,N'-bis(3-methylpyridyl)oxalamide (L¹), N,N'-bis(3-methylpyridyl)adipoamide (L²) and N,N'-bis(3-methylpyridyl)sebacoamide (L³) with tricarboxylic acids and Cu(II) salts afforded {[Cu(L¹)(1,3,5-HBTC)]·H₂O}_n (1,3,5-H₃BTC = 1,3,5-benzenetricarboxylic acid), 1, {[Cu_1.5(L²)_1.5(1,3,5-BTC)(H₂O)₂]·6.5H₂O}_n, 2, [Cu(L²)_0.5(1,3,5-HBTB)]_n (1,3,5-H₃BTB = 1,3,5-tri(4-carboxyphenyl)benzene), 3, [Cu₄(L³)(OH)₂(1,3,5-BTC)₂]_n

SUBMITTER: Lin SY 

PROVIDER: S-EPMC10819037 | biostudies-literature | 2024 Jan

REPOSITORIES: biostudies-literature