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Polymorphism and Red Photoluminescence Emission from 5s² Electron Pairs of Sb(III) in a New One-Dimensional Organic-Inorganic Hybrid Based on Methylhydrazine: MHy₂SbI₅.

ABSTRACT: We explore the crystal structure and luminescent properties of a new 1D organic-inorganic hybrid, MHy₂SbI₅, based on methylhydrazine. The compound reveals the red photoluminescence (PL) originating from the 5s² electron pairs of Sb(III) as well as complex structural behavior. MHy₂SbI₅ crystalizes in two polymorphic forms (I and II) with distinct thermal properties and structural characteristics. Polymorph I adopts the acentric P2₁2₁2₁ chiral space group confirmed by SHG, and, despite a thermally activated disorder of MHy, does not show any phase transitions, while polymorph II undergoes reversible low-temperature phase transition and high-temperature reconstructive tra

SUBMITTER: Rowinska M

PROVIDER: S-EPMC10821241 | biostudies-literature | 2024 Jan

REPOSITORIES: biostudies-literature

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Polymorphism and Red Photoluminescence Emission from 5s² Electron Pairs of Sb(III) in a New One-Dimensional Organic-Inorganic Hybrid Based on Methylhydrazine: MHy₂SbI₅.

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Polymorphism and Red Photoluminescence Emission from 5s2 Electron Pairs of Sb(III) in a New One-Dimensional Organic-Inorganic Hybrid Based on Methylhydrazine: MHy2SbI5.

OmicsDI is part of the ELIXIR infrastructure

Tweets

Polymorphism and Red Photoluminescence Emission from 5s² Electron Pairs of Sb(III) in a New One-Dimensional Organic-Inorganic Hybrid Based on Methylhydrazine: MHy₂SbI₅.