Study on synergistic effects of 4f levels of erbium and black phosphorus/SnNb2O6 heterostructure catalysts by multiple spectroscopic analysis techniques.
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ABSTRACT: Lanthanide single atom modified catalysts are rarely reported because the roles of lanthanide in photocatalysis are difficult to explain clearly. Based on the construction of Er single atom modified black phosphorus/SnNb2O6 (BP/SNO) heterojunctions, the synergistic effect of 4f levels of Er and heterostructures was studied by combining steady-state, transient, and ultrafast spectral analysis techniques with DFT theoretical calculations. According to the Judd-Ofelt theory of lanthanide ions, the CO2 photoreduction test under single wavelength excitation verifies that the 4F7/2/2H11/2 → 4I15/2 emissions of Er in BPEr/SNOEr can be more easily absorbed by SNO and BP, further proving the role of t
SUBMITTER: Li M
PROVIDER: S-EPMC10829003 | biostudies-literature | 2024 Jan
REPOSITORIES: biostudies-literature
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