Hierarchically Porous 3D Freestanding Holey-MXene Framework via Mild Oxidation of Self-Assembled MXene Hydrogel for Ultrafast Pseudocapacitive Energy Storage.

ABSTRACT: The true promise of MXene as a practical supercapacitor electrode hinges on the simultaneous advancement of its three-dimensional (3D) assembly and the engineering of its nanoscopic architecture, two critical factors for facilitating mass transport and enhancing an electrode's charge-storage performance. Herein, we present a straightforward strategy to engineer robust 3D freestanding MXene (Ti₃C₂T_x) hydrogels with hierarchically porous structures. The tetraamminezinc(II) complex cation ([Zn(NH₃)₄]²⁺) is selected to electrostatically assemble colloidal MXene nanosheets into a 3D interconnected hydrogel framework, followed by a mild oxidative acid-etching process to create nanoholes on the MXene surface. These hierarchi

SUBMITTER: Sikdar A 

PROVIDER: S-EPMC10832346 | biostudies-literature | 2024 Jan

REPOSITORIES: biostudies-literature