The synthesis and structural properties of a chlorido-bis-{N-[(4-meth-oxy-phen-yl)imino]-pyrrolidine-1-carboxamide}-zinc(II) (aceto-nitrile)-trichlorido-zincate coordination complex.

ABSTRACT: The title complex, [ZnCl(C₁₂H₁₅N₃O₂)₂][ZnCl₃(CH₃CN)], was synthesized and its structure was fully characterized through single-crystal X-ray diffraction analysis. The complex crystallizes in the ortho-rhom-bic system, space group Pbca (61), with a central zinc atom coordinating one chlorine atom and two pyrrolidinyl-4-meth-oxy-phenyl azoformamide ligands in a bidentate manner, utilizing both the nitro-gen and oxygen atoms in a 1,3-heterodiene (N=N-C=O) motif for coordinative bonding, yielding an overall positively (+1) charged complex. The complex is accompanied by a [(CH₃CN)ZnCl₃]^- counter-ion. The crystal data show that the harder oxygen atoms in the heterodiene zinc chela

SUBMITTER: Tiwari L 

PROVIDER: S-EPMC10833373 | biostudies-literature | 2024 Jan

REPOSITORIES: biostudies-literature