New copper carboxyl-ate pyrene dimers: synthesis, crystal structure, Hirshfeld surface analysis and electrochemical characterization.

ABSTRACT: Two new copper dimers, namely, bis-(dimethyl sulfoxide)-tetra-kis-(μ-pyrene-1-carboxyl-ato)dicopper(Cu-Cu), [Cu₂(C₁₇H₉O₂)₄(C₂H₆OS)₂] or [Cu₂(pyr-COO^-)₄(DMSO)₂] (1), and bis-(di-methyl-formamide)-tetra-kis-(μ-pyrene-1-carboxyl-ato)dicopper(Cu-Cu), [Cu₂(C₁₇H₉O₂)₄(C₃H₇NO)₂] or [Cu₂(pyr-COO^-)₄(DMF)₂] (2) (pyr = pyrene), were synthesized from the reaction of pyrene-1-carb-oxy-lic acid, copper(II) nitrate and tri-ethyl-amine from solvents DMSO and DMF, respectively. While 1 crystallized i

SUBMITTER: Nogue-Guzman VC 

PROVIDER: S-EPMC10833376 | biostudies-literature | 2024 Jan

REPOSITORIES: biostudies-literature