Synthesis, crystal structure and Hirshfeld surface analysis of a cadmium complex of naphthalene-1,5-di-sulfonate and o-phenyl-enedi-amine.

ABSTRACT: A novel o-phenyl-enedi-amine (opda)-based cadmium complex, bis-(benzene-1,2-di-amine-κ² N,N')bis-(benzene-1,2-di-amine-κN)cadmium(II) naphthalene-1,5-di-sulfonate, [Cd(C₆H₈N₂)₄](C₁₀H₆O₆S₂), was synthesized. The complex salt crystallizes in the monoclinic space group C2/c. The Cd atom occupies a special position and coordinates six nitro-gen atoms from four o-phenyl-enedi-amine mol-ecules, two as chelating ligands and two as monodentate ligands. The amino H atoms of opda inter-act with two O atoms of the naphthalene-1,5-di-sulfonate anions. The anions act as bridges between [Cd(opda)₄]²⁺ cations, forming a two-dimensional n

SUBMITTER: Suyunov J 

PROVIDER: S-EPMC10833396 | biostudies-literature | 2023 Dec

REPOSITORIES: biostudies-literature