Synthesis, crystal structure and Hirshfeld analysis of trans-bis-(2-{1-[(6R,S)-3,5,5,6,8,8-hexa-methyl-5,6,7,8-tetra-hydronaphthalen-2-yl]ethyl-idene}-N-methyl-hydrazinecarbo-thio-amidato-κ²N²,S)palladium(II) ethanol monosolvate.

ABSTRACT: The reaction between the (R,S)-fixolide 4-methyl-thio-semicarbazone and Pd^II chloride yielded the title compound, [Pd(C₂₀H₃₀N₃S)₂]·C₂H₆O {common name: trans-bis-[(R,S)-fixolide 4-methyl-thio-semicarbazonato-κ² N ² S]palladium(II) ethanol monosolvate}. The asymmetric unit of the title compound consists of one bis-thio-semicarbazonato Pd^II complex and one ethanol solvent mol-ecule. The thio-semicarbazononato ligands act as metal chelators with a trans configuration in a distorted square-planar geometry. A C-H⋯S intra-molecular inter-action, with graph-set motif S(6), is observed and the coordination sphere resembles a hyd

SUBMITTER: de Melo APL 

PROVIDER: S-EPMC10833400 | biostudies-literature | 2023 Dec

REPOSITORIES: biostudies-literature