Crystal structure and Hirshfeld surface analysis of a new mononuclear copper(II) complex: [bis-(pyridin-2-yl-κN)amine](formato-κO)(m-hy-droxy-benzoato-κ²O,O')copper(II).

ABSTRACT: A new mononuclear copper(II) complex, [Cu(C₇H₅O₃)(HCO₂)(C₁₀H₉N₃)], containing mixed N- and O-donor ligands, 2,2'-di-pyridyl-amine (dpyam) and m-hy-droxy-benzoate (m-OHbenz), has been obtained from a solvent mixture. The coordination environment of the Cu^II ion is distorted square-pyramidal with a [N₂O₃] coordination set originating from the chelating dpyam and m-OHbenz ligands in the basal plane and the O atom of a formato ligand at the apical position. The crystal structure of the title complex is stabilized by N-H⋯O, O-H⋯O, C-H⋯O hydrogen-bonding, π-π and C-H⋯π inter-molecular inter-actions, which were qu-anti-fied by Hirshfeld sur

SUBMITTER: Chaisuriya W 

PROVIDER: S-EPMC10833405 | biostudies-literature | 2023 Dec

REPOSITORIES: biostudies-literature