Synthesis, crystal structure and Hirshfeld surface analysis of the tetra-kis complex NaNdPyr₄(i-PrOH)₂·i-PrOH with a carbacyl-amido-phosphate of the amide type.

ABSTRACT: The tetra-kis complex of neodymium(III), tetra-kis-{μ-N-[bis-(pyrrolidin-1-yl)phos-phor-yl]acet-am-id-ato}bis(pro-pan-2-ol)neodymiumsodium pro-pan-2-ol monosol-vate, [NaNd(C₁₀H₁₆Cl₃N₃O₂)₄(C₃H₈O)₂]·C₃H₈O or NaNdPyr₄(i-PrOH)₂·i-PrOH, with the amide type CAPh ligand bis(N,N-tetra-methylene)(tri-chloro-acetyl)phos-phoric acid tri-amide (HPyr), has been synthesized, crystallized and characterized by X-ray diffraction. The complex does not have the tetra-kis-(CAPh)lanthanide anion, which is typical for ester-type CAPh-based coordin-ation compounds. Instead, the NdO₈ polyhedron is formed by one oxygen atom of a

SUBMITTER: Kariaka NS 

PROVIDER: S-EPMC10833406 | biostudies-literature | 2023 Dec

REPOSITORIES: biostudies-literature