A zero-valent palladium cluster-organic framework.

ABSTRACT: Acquiring spatial control of nanoscopic metal clusters is central to their function as efficient multi-electron catalysts. However, dispersing metal clusters on surfaces or in porous hosts is accompanied by an intrinsic heterogeneity that hampers detailed understanding of the chemical structure and its relation to reactivities. Tethering pre-assembled molecular metal clusters into polymeric, crystalline 2D or 3D networks constitutes an unproven approach to realizing ordered arrays of chemically well-defined metal clusters. Herein, we report the facile synthesis of a {Pd₃} cluster-based organometallic framework from a molecular triangulo-Pd₃(CNXyl)₆ (Xyl = xylyl; Pd₃) cluster under chemically mild conditions. The formally zero-valent Pd₃

SUBMITTER: Liu X 

PROVIDER: S-EPMC10853280 | biostudies-literature | 2024 Feb

REPOSITORIES: biostudies-literature