Bond Trading: Intramolecular Metal and Ligand Exchange within a NO/Ni/Co Complex.

ABSTRACT: With the goal of generating hetero-redox levels on metals as well as on nitric oxide (NO), metallodithiolate (N₂ S₂ )Co^III (NO^- ), N₂ S₂ = N,N- dibenzyl-3,7-diazanonane-1,9-dithiolate, is introduced as ligand to a well-characterized labile [Ni⁰ (NO)⁺ ] synthon. The reaction between [Ni⁰ (NO⁺ )] and [Co^III (NO^- )] has led to a remarkable electronic and ligand redistribution to form a heterobimetallic dinitrosyl cobalt [(N₂ S₂ )Ni^II ∙Co(NO)₂ ]⁺ complex with formal two electron oxidation state switches concomitant with the nickel extraction or transfer as Ni^II into the N₂ S₂ l

SUBMITTER: Jana M 

PROVIDER: S-EPMC10853699 | biostudies-literature | 2024 Feb

REPOSITORIES: biostudies-literature