Generating active metal/oxide reverse interfaces through coordinated migration of single atoms.

ABSTRACT: Identification of active sites in catalytic materials is important and helps establish approaches to the precise design of catalysts for achieving high reactivity. Generally, active sites of conventional heterogeneous catalysts can be single atom, nanoparticle or a metal/oxide interface. Herein, we report that metal/oxide reverse interfaces can also be active sites which are created from the coordinated migration of metal and oxide atoms. As an example, a Pd₁/CeO₂ single-atom catalyst prepared via atom trapping, which is otherwise inactive at 30 °C, is able to completely oxidize formaldehyde after steam treatment. The enhanced reactivity is due to the formation of a Ce₂O₃-Pd nanoparticle domain interface, which is generated by the migration of bo

SUBMITTER: Zhang L 

PROVIDER: S-EPMC10858022 | biostudies-literature | 2024 Feb

REPOSITORIES: biostudies-literature