Salt-Induced Diffusion of Star and Linear Polyelectrolytes within Multilayer Films.

ABSTRACT: This study explores the effect of salt on the diffusivity of polyelectrolytes of varied molecular architecture in layer-by-layer (LbL) films in directions parallel and perpendicular to the substrate using fluorescence recovery after photobleaching (FRAP) and neutron reflectivity (NR) techniques, respectively. A family of linear, 4-arm, 6-arm, and 8-arm poly(methacrylic acids) (LPMAA, 4PMAA, 6PMAA, and 8PMAA, respectively) of matched molecular weights were synthesized using atom transfer radical polymerization and assembled with a linear polycation, poly[2-(trimethylammonium)ethyl methacrylate chloride] (QPC). NR studies involving deuterated QPC revealed ∼10-fold higher polycation mobility for the 8PMAA/QPC system compared to all-linear LbL films upon exposure to 0.25 M NaCl solution

SUBMITTER: Aliakseyeu A 

PROVIDER: S-EPMC10863069 | biostudies-literature | 2023 Jul

REPOSITORIES: biostudies-literature