Coordination-induced O-H/N-H bond weakening by a redox non-innocent, aluminum-containing radical.

ABSTRACT: Several renewable energy schemes aim to use the chemical bonds in abundant molecules like water and ammonia as energy reservoirs. Because the O-H and N-H bonds are quite strong (>100 kcal/mol), it is necessary to identify substances that dramatically weaken these bonds to facilitate proton-coupled electron transfer processes required for energy conversion. Usually this is accomplished through coordination-induced bond weakening by redox-active metals. However, coordination-induced bond weakening is difficult with earth's most abundant metal, aluminum, because of its redox inertness under mild conditions. Here, we report a system that uses aluminum with a redox non-innocent ligand to achieve significant levels of coordination-induced bond weakening of O-H and N-H bonds. The multisite proton

SUBMITTER: Sinhababu S 

PROVIDER: S-EPMC10864259 | biostudies-literature | 2024 Feb

REPOSITORIES: biostudies-literature