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Straightforward Assessment of Wettability Changes by Washburn Capillary Rise: Toward a Screening Tool for Selecting Water Compositions for Improved Oil Recovery.


ABSTRACT: Evaluating the wettability state of reservoir rocks is key for understanding and optimizing waterflooding and improved oil recovery techniques that imply the use of low-salinity water. Aside from established petrophysical techniques, such as Amott imbibition tests, we evaluated the Washburn capillary rise method as a low-cost, easy-to-implement, and rapid screening tool for probing the wettability state of rock samples. The well-known limitations of this method are discussed and circumvented. We show that measuring the capillary rise of two liquids -brine and n-octane-is required to assess the evolution of the wettability state of a material induced by various treatments. The wettability state is quantified by the adhesion tension of brine to the solid. The higher the adhesion tension of brine, the more water-wet the sample. An increase in oil-wetness is observed when the sample is contacted with a crude oil or its released waters; an increase in water-wetness is obtained by postcontacting the oil-wet sample with low-salinity brine or surfactant solutions. The Washburn capillary rise is revealed to be a robust method for screening wettability alteration. With a typical duration of 1-10 min, it allows reproducibility check and screening of a wide range of brine compositions in a reasonable time frame. Therefore, it is a relevant tool to identify the most favorable brine compositions to be tested afterward with more time-consuming techniques, such as Amott tests and corefloods.

SUBMITTER: Molinier V 

PROVIDER: S-EPMC10870297 | biostudies-literature | 2024 Feb

REPOSITORIES: biostudies-literature

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Straightforward Assessment of Wettability Changes by Washburn Capillary Rise: Toward a Screening Tool for Selecting Water Compositions for Improved Oil Recovery.

Molinier Valérie V   Pauliet Laura L   Klimenko Alexandra A   Passade-Boupat Nicolas N   Bourrel Maurice M  

ACS omega 20240203 6


Evaluating the wettability state of reservoir rocks is key for understanding and optimizing waterflooding and improved oil recovery techniques that imply the use of low-salinity water. Aside from established petrophysical techniques, such as Amott imbibition tests, we evaluated the Washburn capillary rise method as a low-cost, easy-to-implement, and rapid screening tool for probing the wettability state of rock samples. The well-known limitations of this method are discussed and circumvented. We  ...[more]

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