Polymer-Coated Covalent Organic Frameworks as Porous Liquids for Gas Storage.

ABSTRACT: Several synthetic methods have recently emerged to develop high-surface-area solid-state organic framework-based materials into free-flowing liquids with permanent porosity. The fluidity of these porous liquid (PL) materials provides them with advantages in certain storage and transport processes. However, most framework-based materials necessitate the use of cryogenic temperatures to store weakly bound gases such as H₂, temperatures where PLs lose their fluidity. Covalent organic framework (COF)-based PLs that could reversibly form stable complexes with H₂ near ambient temperatures would represent a promising development for gas storage and transport applications. We report here the development, characterization, and evaluation of a material with these remarkable cha

SUBMITTER: Mow RE 

PROVIDER: S-EPMC10870717 | biostudies-literature | 2024 Feb

REPOSITORIES: biostudies-literature