Unknown

Dataset Information

0

[Br4F21]- - a unique molecular tetrahedral interhalogen ion containing a μ4-bridging fluorine atom surrounded by BrF5 molecules.

ABSTRACT: The reaction of [NMe4][BrF6] with an excess of BrF5 leads to the compound [NMe4][Br4F21]·BrF5. It features molecular [(μ4-F)(BrF5)4]- anions of tetrahedron-like shape containing central μ4-bridging F atoms coordinated by four BrF5 molecules. It is the most BrF5-rich fluoridobromate anion by mass. Quantum-chemical calculations showed that the μ4-F-Br bonds within the anion are essentially ionic in nature. The compound is the first example where F atoms bridge μ4-like neither to metal nor to hydrogen atoms. It was characterized by Raman spectroscopy and by single-crystal X-ray diffraction. The latter showed surprisingly that its crystal structure is related to the intermetallic half-Heusler compound and structure type MgAgAs.

SUBMITTER: Mobs M 

PROVIDER: S-EPMC10901516 | biostudies-literature | 2024 Feb

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

[Br<sub>4</sub>F<sub>21</sub>]<sup>-</sup> - a unique molecular tetrahedral interhalogen ion containing a μ<sub>4</sub>-bridging fluorine atom surrounded by BrF<sub>5</sub> molecules.

Möbs Martin M   Graubner Tim T   Karttunen Antti J AJ   Kraus Florian F  

Chemical science 20240120 9

The reaction of [NMe<sub>4</sub>][BrF<sub>6</sub>] with an excess of BrF<sub>5</sub> leads to the compound [NMe<sub>4</sub>][Br<sub>4</sub>F<sub>21</sub>]·BrF<sub>5</sub>. It features molecular [(μ<sub>4</sub>-F)(BrF<sub>5</sub>)<sub>4</sub>]<sup>-</sup> anions of tetrahedron-like shape containing central μ<sub>4</sub>-bridging F atoms coordinated by four BrF<sub>5</sub> molecules. It is the most BrF<sub>5</sub>-rich fluoridobromate anion by mass. Quantum-chemical calculations showed that the μ<  ...[more]

Similar Datasets

Unknown Spectroscopic Study of the Br<sup>-</sup> +CH<sub>3</sub> I→I<sup>-</sup> +CH<sub>3</sub> Br S<sub>N</sub> 2 Reaction.
| S-EPMC9804238 | biostudies-literature
Unknown An interacting quantum atom study of model S<sub>N</sub> 2 reactions (X<sup>-</sup> ···CH<sub>3</sub> X, X = F, Cl, Br, and I).
| S-EPMC5836863 | biostudies-literature
Unknown FLi&lt;sub&gt;4&lt;/sub&gt;X&lt;sub&gt;4&lt;/sub&gt;&lt;sup&gt;-&lt;/sup&gt; (X = Cl, Br, I): Superhalogen Anions with Planar Tetracoordinate Fluorine.
| S-EPMC11643589 | biostudies-literature
Unknown Construction of Full-Spectrum-Response Bi<sub>3</sub>O<sub>4</sub>Br:Er<sup>3+</sup>@Bi<sub>2</sub>O<sub>3-</sub> <sub>x</sub> S-Scheme Heterojunction With [Bi─O] Tetrahedral Sharing by Integrated Upconversion and Photothermal Effect Toward Optimized Photocatalytic Performance.
| S-EPMC11848554 | biostudies-literature
Unknown CH<sub>4</sub> activation by PtX<sup>+</sup> (X = F, Cl, Br, I).
| S-EPMC9548706 | biostudies-literature
Unknown Insights into the structures and electronic properties of Cu<sub>n+1</sub><sup>μ</sup> and Cu<sub>n</sub>S <sup>μ</sup> (n = 1-12; μ = 0, ±1) clusters.
| S-EPMC5430952 | biostudies-literature
Unknown Linking of Cu<sup>I</sup> Units by Tetrahedral Mo<sub>2</sub> E<sub>2</sub> Complexes (E=P, As).
| S-EPMC7756472 | biostudies-literature
Unknown Fe<sup>3+</sup> in a tetrahedral position determined the electrocatalytic properties in FeMn<sub>2</sub>O<sub>4</sub>.
| S-EPMC9510904 | biostudies-literature
Unknown Hydrogen-Atom Transfer Oxidation with H<sub>2</sub>O<sub>2</sub> Catalyzed by [FeII(1,2-bis(2,2'-bipyridyl-6-yl)ethane(H<sub>2</sub>O)<sub>2</sub>]<sup>2+</sup>: Likely Involvement of a (μ-Hydroxo)(μ-1,2-peroxo)diiron(III) Intermediate.
| S-EPMC5765857 | biostudies-literature
Unknown Br<sup>-</sup>/BrO<sup>-</sup>-mediated highly efficient photoelectrochemical epoxidation of alkenes on α-Fe<sub>2</sub>O<sub>3</sub>.
| S-EPMC10082182 | biostudies-literature