Twisting two-dimensional iron sulfide layers into coincident site superlattices via intercalation chemistry.

ABSTRACT: Layered van der Waals (vdW) materials are susceptible not only to various stacking polymorphs through translations but also twisted structures due to rotations between layers. Here, we study the influence of such layer-to-layer twisting through the intercalation of ethylenediamine (EDA) molecules into tetragonal iron sulfide (Mackinawite FeS). Selected area electron diffraction patterns of intercalated FeS display reflections corresponding to multiple square lattices with a fixed angle between them, contrary to a single square lattice seen in the unintercalated phase. The observed twist angles of 49.13° and 22.98° result from a superstructure formation well described by the coincident site lattice (CSL) theory. According to the CSL theory, these measured twist angles lead to the formation of larger coincident site supercells. We build these CSL models for FeS using crystallographic group-subgroup transformations and find simulated electron diffraction patterns from the model to agree with the experimentally measured data.

SUBMITTER: Balisetty L 

PROVIDER: S-EPMC10901521 | biostudies-literature | 2024 Feb

REPOSITORIES: biostudies-literature