Recyclable Curcumin-Based Bioepoxy Resin with On-Demand Chemical Cleavability.

ABSTRACT: We synthesized a novel curcumin-based bioepoxy resin by introducing epichlorohydrin (ECH) into the hydroxyl groups of curcumin and analyzed it using Fourier transform infrared spectroscopy (FTIR) and nuclear magnetic resonance (NMR). The epoxy equivalent weight (EEW) was determined based on a reaction with sodium hydroxide (NaOH) through titration, and the actual curing process was conducted after exploring the optimal conditions using an amine-based curing agent through dynamic scanning in differential scanning calorimetry (DSC) and isotherm analysis. The cured epoxy resin had a tensile strength, Young's modulus, and glass transition temperature (T_g) of 33 MPa, 1.4 GPa, and 86 °C, respectively. Interestingly, the diunsaturated ketone contained in the epoxy resin showed o

SUBMITTER: Jeong J 

PROVIDER: S-EPMC10905686 | biostudies-literature | 2024 Feb

REPOSITORIES: biostudies-literature