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A mild protocol for efficient preparation of functional molecules containing triazole.

ABSTRACT: The construction of a class of novel triazole molecules containing sulfonyl fluoride functionalities was achieved through Cu-catalyzed click chemistry in good to excellent yields. The sulfonyl fluoride moieties were cleaved completely under base conditions to produce N-unsubstituted triazoles quantitatively, which provides a strategy to combine SuFEx click chemistry with Cu-catalyzed click chemistry ingeniously.

SUBMITTER: Leng J 

PROVIDER: S-EPMC10911410 | biostudies-literature | 2024 Feb

REPOSITORIES: biostudies-literature

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A mild protocol for efficient preparation of functional molecules containing triazole.

Leng Jing J   Xu Jie J   Li Yanan Y   Wang Shi-Meng SM   Qin Hua-Li HL  

RSC advances 20240201 11

The construction of a class of novel triazole molecules containing sulfonyl fluoride functionalities was achieved through Cu-catalyzed click chemistry in good to excellent yields. The sulfonyl fluoride moieties were cleaved completely under base conditions to produce <i>N</i>-unsubstituted triazoles quantitatively, which provides a strategy to combine SuFEx click chemistry with Cu-catalyzed click chemistry ingeniously. ...[more]

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