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(2,2'-Bi-pyridine-κ2N,N')(4,4'-dimeth-oxy-2,2'-bipyridine-κ2N,N')palladium(II) bis-(tri-fluoro-meth-anesulfonate).

ABSTRACT: In the title complex salt, [Pd(C10H8N2)(C12H12N2O2)](CF3SO3)2, the palladium(II) atom is fourfold coordinated by two chelating ligands, 2,2'-bi-pyridine and 4,4'-dimeth-oxy-2,2'-bi-pyridine, in a distorted square-planar environment. In the crystal, weak π-π stacking inter-actions between the 2,2'-bi-pyridine rings [centroid-to-centroid distances = 3.8984 (19) Å] and between the 4,4'-dimeth-oxy-2,2'-bi-pyridine rings [centroid-to-centroid distances = 3.747 (18) Å] contribute to the alignment of the complex cations in columns parallel to the b-axis direction.

SUBMITTER: Vargas BB 

PROVIDER: S-EPMC10915546 | biostudies-literature | 2024 Feb

REPOSITORIES: biostudies-literature

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(2,2'-Bi-pyridine-κ<sup>2</sup><i>N</i>,<i>N</i>')(4,4'-dimeth-oxy-2,2'-bipyridine-κ<sup>2</sup><i>N</i>,<i>N</i>')palladium(II) bis-(tri-fluoro-meth-anesulfonate).

Vargas Brittney B BB   Arman Hadi D HD   Adrian Rafael A RA  

IUCrData 20240208 Pt 2

In the title complex salt, [Pd(C<sub>10</sub>H<sub>8</sub>N<sub>2</sub>)(C<sub>12</sub>H<sub>12</sub>N<sub>2</sub>O<sub>2</sub>)](CF<sub>3</sub>SO<sub>3</sub>)<sub>2</sub>, the palladium(II) atom is fourfold coordinated by two chelating ligands, 2,2'-bi-pyridine and 4,4'-dimeth-oxy-2,2'-bi-pyridine, in a distorted square-planar environment. In the crystal, weak π-π stacking inter-actions between the 2,2'-bi-pyridine rings [centroid-to-centroid distances = 3.8984 (19) Å] and between the 4,4'-dime  ...[more]

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