(2,2'-Bi-pyridine-κ²N,N')(4,4'-dimeth-oxy-2,2'-bipyridine-κ²N,N')palladium(II) bis-(tri-fluoro-meth-anesulfonate).

ABSTRACT: In the title complex salt, [Pd(C₁₀H₈N₂)(C₁₂H₁₂N₂O₂)](CF₃SO₃)₂, the palladium(II) atom is fourfold coordinated by two chelating ligands, 2,2'-bi-pyridine and 4,4'-dimeth-oxy-2,2'-bi-pyridine, in a distorted square-planar environment. In the crystal, weak π-π stacking inter-actions between the 2,2'-bi-pyridine rings [centroid-to-centroid distances = 3.8984 (19) Å] and between the 4,4'-dimeth-oxy-2,2'-bi-pyridine rings [centroid-to-centroid distances = 3.747 (18) Å] contribute to the alignment of the complex cations in columns parallel to the b-axis direction.

SUBMITTER: Vargas BB 

PROVIDER: S-EPMC10915546 | biostudies-literature | 2024 Feb

REPOSITORIES: biostudies-literature