[4-(2-Aminoethyl)morpholine-κ²N,N']di-bromidocadmium(II): synthesis, crystal structure and Hirshfeld surface analysis.

ABSTRACT: The title compound, [CdBr₂(C₆H₁₄N₂O)], was synthesized upon complexation of 4-(2-aminoethyl)morpholine and cadmium(II) bromide tetra-hydrate at 303 K. It crystallizes as a centrosymmetric dimer, with one cadmium atom, two bromine atoms and one N,N'-bidentate 4-(2-aminoethyl)morpholine ligand in the asymmetric unit. The metal atom is six-coordinated and has a distorted octa-hedral geometry. In the crystal, O⋯Cd inter-actions link the dimers into a polymeric double chain and inter-molecular C-H⋯O hydrogen bonds form R ₂ ²(6) ring motifs. Further C-H⋯Br and N-H⋯Br hydrogen bonds link the components into a three-dimensional network. As the N-H⋯Br hydrogen bonds are shorter than the C-H⋯Br inter-actions, they

SUBMITTER: Chidambaranathan B 

PROVIDER: S-EPMC10915673 | biostudies-literature | 2024 Mar

REPOSITORIES: biostudies-literature