Chemically Engineered Titanium Oxide Interconnecting Layer for Multijunction Polymer Solar Cells.

ABSTRACT: We report chemically tunable n-type titanium oxides using ethanolamine as a nitrogen dopant source. As the amount of ethanolamine added to the titanium oxide precursor during synthesis increases, the Fermi level of the resulting titanium oxides (ethanolamine-incorporated titanium oxides) significantly changes from -4.9 eV to -4.3 eV, and their free charge carrier densities are enhanced by two orders of magnitudes, reaching up to 5 × 10¹⁸ cm^-3. Unexpectedly, a basic ethanolamine reinforces not only the n-type properties of titanium oxides, but also their basicity, which facilitates acid-base ionic junctions in contact with acidic materials. The enhanced charge carrier density and basicity of the chemically tuned titanium oxides enable multi-junction solar cells to have

SUBMITTER: Kim G 

PROVIDER: S-EPMC10935189 | biostudies-literature | 2024 Feb

REPOSITORIES: biostudies-literature