Dehydration kinetics of nanoconfined water in beryl probed by high temperature single crystal synchrotron X-ray diffraction.

ABSTRACT: Understanding changes in material properties through external stimuli plays a key role in validating the expected performance of materials and engineering material properties in a controlled manner. Here, we introduce a fundamental protocol to deduce dehydration reactions kinetics of water confined in nanopore channels, with the cyclosilicate beryl as the scaffold of interest, using time-resolved synchrotron X-ray diffraction (SXRD), in the temperature interval of 298-1038 K. The temperature-dependent intensity ( I ) of the strongest reflection (112) was used as the crystallite variable. An estimation of an isobaric thermal crystallite coefficient, k , analogous with the isobaric thermal expansion coefficient, established the rate of relative crystallization as a function of temperature, ∂ I ∂ T . A plot of lnk and 1 T gives rise to two kinetic steps, indicating a slow dehydration stage up to ~ 700 K and a fast dehydration stage up to the investigated temperature 1038 K. The crystal structure of beryl determined up to 1038 K, in temperature increment as small as 10 K, indicates the presence of channel ions Na and Fe and a gradual decrease of water upon heating.

SUBMITTER: Nguyen PQH 

PROVIDER: S-EPMC10937911 | biostudies-literature | 2024 Mar

REPOSITORIES: biostudies-literature