Using Solution History to Control Hydrogel Properties of a Perylene Bisimide.

ABSTRACT: pH dependence on water soluble aggregates is well-known in the field of low molecular weight gelators (LMWGs), with different aggregates sometimes having very different properties depending on their final pH. This aggregation determines their applications and performance. Here, we investigate the pH dependence of perylene bisimide gels; initially solutions are formed at a high pH and gels form as the pH is decreased. We find it is not only the final pH but also the starting pH that can impact the resulting gel. We use small angle neutron scattering (SANS), rheology, ¹ H NMR spectroscopy and absorption spectroscopy to examine the effect of starting pH on gelation kinetics and final gel properties. Adjusting the solution from pH 9 (where there are few or no aggregates) to pH 6 res

SUBMITTER: Ginesi RE 

PROVIDER: S-EPMC10947066 | biostudies-literature | 2023 Jul

REPOSITORIES: biostudies-literature