Dataset Information

Sustainable Green Route for Activated Carbon Synthesis from Biomass Waste for High-Performance Supercapacitors.

ABSTRACT: Supercapacitors are high-power energy storage devices due to their charge storage capability and long cyclic stability. These devices rely on highly porous materials for electrodes providing a substantial surface area per mass, such as highly porous carbon. Developing high-performance porous carbon from biomass wastes such as waste-activated sludge and spent coffee is a sustainable way to reduce adverse environmental effects, contributing toward a carbon circular economy. In this study, hierarchically porous carbon with a high surface area of 1198 ± 60 m² g^-1 was synthesized through a green route. Sodium acetate was utilized as an environmentally friendly electrolyte. The long-term stability test at a high current density was conducted, providing valuable insights into the viability of sodium acetate as a robust electrolyte in supercapacitor application. The supercapacitor demonstrated an excellent cycle stability of 98.4% after 20,000 cycles at a current density of 10 A g^-1 in sodium acetate. Further assessment revealed dominant fast surface kinetics. Moreover, a maximum energy density of 15.9 Wh kg^-1 at 0.2 A g^-1 was achieved. By utilizing highly porous carbon in conjunction with a water-based binder, a substantial improvement of 76% in capacity with respect to a nonaqueous-based binder was demonstrated.

SUBMITTER: Jafari M

PROVIDER: S-EPMC10955698 | biostudies-literature | 2024 Mar

REPOSITORIES: biostudies-literature

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Sustainable Green Route for Activated Carbon Synthesis from Biomass Waste for High-Performance Supercapacitors.

Jafari Maasoomeh M Botte Gerardine G GG

ACS omega 20240308 11

Supercapacitors are high-power energy storage devices due to their charge storage capability and long cyclic stability. These devices rely on highly porous materials for electrodes providing a substantial surface area per mass, such as highly porous carbon. Developing high-performance porous carbon from biomass wastes such as waste-activated sludge and spent coffee is a sustainable way to reduce adverse environmental effects, contributing toward a carbon circular economy. In this study, hierarch ...[more]

PMID: 38524414

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Project description:Currently, comparisons between biochar and activated carbon in terms of performance, environmental impacts as well as financial implications are limited. In this study, biochar sourced from date palm waste were analysed using gate-to-grave life cycle assessment approach and results were compared to activated carbon derived from woody biomass. Simapro 8.5 software was used to quantitatively simulate the environmental impacts of both adsorbents. Date palm waste biochar and activated carbon global warming potentials (GWPs) were found to be 1.53 and 8.96 kg CO2eq/kg respectively. The cumulative energy demand (CED) for producing date palm waste biochar was found to be 20.3 MJ/kg, whereas, activated carbon resulted in 119.5 MJ/kg. Both adsorbents’ performance in terms of adsorption capacity were compared, and it was found that biochar is comparable with activated carbon. The economic performance demonstrated that the average cost of production of date palm waste biochar and activated carbon were $1.06/kg and $1.34/kg, respectively. Sensitivity analysis showed that when the source of energy was changed to renewable energy, a CED dropped to 105.2 MJ/kg and 7.68 MJ/kg, a GWP dropped to 7.29 kg CO2 eq. and 0.665 kg CO2 eq. and production costs dropped to $1.30 and to $1.04 for producing activated carbon and biochar respectively. Based on the results of the study, date palm waste biochar is more cost-effective, shows less environmental impact, and has comparable adsorption efficiency as compared to activated carbon. Graphical abstract Image 1 Highlights • Biochar GWP was 2.36 kg CO2eq/kg and activated carbon GWP was 8.34 kg CO2eq/kg.• Biochar CED was 20.3 MJ/kg and activated carbon CED was 119.5 MJ/kg.• Adsorption capacities of biochar were comparable with activated carbon.• Production cost of biochar was $1.06/kg and activated carbon was $1.34/kg.• Sensitivity analysis showed that switching solar energy reduced CED and GWP. Adsorption capacity; environmental impact; disposal; cost efficiency; sensitivity analysis.

Project description:Carbon materials derived from marine waste have been drawing attention for supercapacitor applications. In this work, chitins from squid and prawn marine wastes were used as carbon precursors for further application as electrodes for energy storage devices. Chitins were obtained through a deproteinization method based on enzymatic hydrolysis as an alternative to chemical hydrolysis as commonly presented in the literature. The obtained porous carbons were characterized using a BET surface area analyzer to determine the specific surface area and pore size, as well as scanning electron microscopy (SEM) with energy dispersive X-ray analysis (EDX), transmission electron microscopy (TEM), Raman spectroscopy, attenuated total reflectance Fourier transform infrared (ATR-FTIR) spectroscopy, X-ray diffraction (XRD), and X-ray photoelectron spectroscopy (XPS), to characterize their morphology, composition, and structure. The electrochemical characterization was performed using a glassy carbon (GC) electrode modified with marine waste-based porous carbons as the working electrode through cyclic voltammetry and galvanostatic charge/discharge using ethaline, a choline chloride-based deep eutectic solvent (DES), as an eco-friendly and sustainable electrolyte. Squid and prawn chitin-based carbons presented a surface area of 149.3 m2 g-1 and 85.0 m2 g-1, pore volume of 0.053 cm3 g-1 and 0.029 cm3 g-1, and an associated specific capacitance of 20 and 15 F g-1 at 1 A g-1, respectively. Preliminary studies were performed to understand the effect of -OH groups on the chitin-based carbon surface with DES as an electrolyte, as well as the effect of aqueous electrolytes (1 mol L-1 sulphuric acid (H2SO4) and 1 mol L-1 potassium hydroxide (KOH)) on the capacitance and retention of the half-cell set up. It is provided, for the first time, the use of chitin-based carbon materials obtained through a one-step carbonization process combined with an eco-friendly DES electrolyte for potential application in energy storage devices.

Dataset Information

Sustainable Green Route for Activated Carbon Synthesis from Biomass Waste for High-Performance Supercapacitors.

Publications

Sustainable Green Route for Activated Carbon Synthesis from Biomass Waste for High-Performance Supercapacitors.

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