Bidispersity Improves the Toughness and Impact Resistance of Star-Polymer Thin Films.

ABSTRACT: Branched polymer architectures are used to tune the mechanical properties of impact-resistant thin films through parameters, such as chain length and grafting density. While chain dispersity affects molecular properties, such as interpenetration and entanglements, structure-property relationships accounting for dispersity are challenging to obtain experimentally and are often neglected in computational models. We employ molecular dynamics simulations to model the high-rate tensile elongation and nanoballistic impact of thin films composed of bidisperse star polymers with varying arm lengths. We find that, at fixed molecular weight, high dispersity can significantly enhance the toughness and impact resistance of the films without decreasing their elastic modulus. Bidisperse stars with fewer

SUBMITTER: Gurel U 

PROVIDER: S-EPMC10956491 | biostudies-literature | 2024 Mar

REPOSITORIES: biostudies-literature