Water-participated mild oxidation of ethane to acetaldehyde.

ABSTRACT: The direct conversion of low alkane such as ethane into high-value-added chemicals has remained a great challenge since the development of natural gas utilization. Herein, we achieve an efficient one-step conversion of ethane to C₂ oxygenates on a Rh₁/AC-SNI catalyst under a mild condition, which delivers a turnover frequency as high as 158.5 h^-1. ¹⁸O isotope-GC-MS shows that the formation of ethanol and acetaldehyde follows two distinct pathways, where oxygen and water directly participate in the formation of ethanol and acetaldehyde, respectively. In situ formed intermediate species of oxygen radicals, hydroxyl radicals, vinyl groups, and ethyl groups are captured by laser desorption ionization/time of flight mass spectrometer. Density function

SUBMITTER: Li B 

PROVIDER: S-EPMC10959925 | biostudies-literature | 2024 Mar

REPOSITORIES: biostudies-literature