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TiO2 supported pallidum-bipyridyl complex as an efficient catalyst for Suzuki-Miyaura reaction in aqueous-ethanol.


ABSTRACT: Owing to their improved catalytic stability and ability to undergo repeated cycles, solid-supported catalysts show great potential for various catalytic reactions. In this study, we synthesized a catalyst comprising a palladium-2,2-bipyridine complex supported on TiO2 nanoparticles (TiO2@BDP-PdCl2) fully characterised and investigated its efficacy in Suzuki-Miyaura cross coupling reactions involving phenyl boronic acid with various aryl halides under mild reaction conditions. The 2,2'- bipyridine (bp) has shown excellent complexation properties for Pd (II) and it could be easily anchored onto functionalized TiO2 support by the bridging carboxylate ions. The composition and structure of the as-prepared catalyst was characterized by powder X-ray di

SUBMITTER: Gandra UR 

PROVIDER: S-EPMC10973498 | biostudies-literature | 2024 Mar

REPOSITORIES: biostudies-literature