Influence of the Rare Earth Cation on the Magnetic Properties of Layered 12R-Ba₄M⁴⁺Mn₃O₁₂ (M = Ce, Pr) Perovskites.

ABSTRACT: Material design is increasingly used to realize desired functional properties, and the perovskite structure family is one of the richest and most diverse: perovskites are employed in many applications due to their structural flexibility and compositional diversity. Hexagonal, layered perovskite structures with chains of face-sharing transition metal oxide octahedra have attracted great interest as quantum materials due to their magnetic and electronic properties. Ba₄MMn₃O₁₂, a member of the "12R" class of hexagonal, layered perovskites, contains trimers of face-sharing MnO₆ octahedra that are linked by a corner-sharing, bridging MO₆ octahedron. Here, we investigate cluster magnetism in the Mn₃O₁₂ trimers and the r

SUBMITTER: Dzara MJ 

PROVIDER: S-EPMC10976642 | biostudies-literature | 2024 Mar

REPOSITORIES: biostudies-literature