4-Fluoro-2-(phenylamino)benzoic acid
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ABSTRACT:
SUBMITTER: Li J
PROVIDER: S-EPMC10993557 | biostudies-literature | 2024 Mar
REPOSITORIES: biostudies-literature
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Project description:In the title compound, C7H4F2O3, an intra-molecular O-H?O hydrogen bond is observed. In the crystal, inversion dimers linked by pairs of O-H?O hydrogen bonds generate R 2 (2)(8) ring motifs. These dimers are linked by C-H?O and C-H?F hydrogen bonds, forming sheets lying parallel to (30-1). The sheets are linked by aromatic ?-? stacking inter-actions [inter-centroid distance = 3.7817?(9)?Å], forming a three-dimensional structure.
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Project description:In the title compound, C(15)H(11)FO(3), the aromatic rings are oriented at a dihedral angle of 69.26 (3)°. In the crystal structure, inversion dimers arise from pairs of inter-molecular O-H⋯O hydrogen bonds, and C-H⋯O hydrogen bonds further consolidate the packing. There are also C-H⋯π contacts between the benzoic acid and 2-fluoro-benzene rings.
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Project description:The title compound, C(15)H(11)FO(2), is an important inter-mediate in the synthesis of side-chain ligands for polymeric liquid crystals. The vinyl group is almost coplanar with both the aromatic rings. The crystal structure is stabilized by inter-molecular O-H⋯O hydrogen bonding.
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Project description:In the title compound, C(14)H(10)FNO(2), the benzene rings make a dihedral angle of 57.50 (13)°, and the molecule has an E configuration about the C=N bond. In the crystal, molecules are linked via pairs of O-H⋯O hydrogen bonds, forming inversion dimers.
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