Construction of magnetic MoS2/NiFe2O4/MIL-101(Fe) hybrid nanostructures for separation of dyes and antibiotics from aqueous media† † Electronic supplementary information (ESI) available. See DOI: https://doi.org/10.1039/d4ra00505h
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ABSTRACT:
SUBMITTER: Moradi-Bieranvand M
PROVIDER: S-EPMC10995676 | biostudies-literature | 2024 Apr
REPOSITORIES: biostudies-literature
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Project description:The electrochemical synthesis of metal-organic frameworks (MOFs) has been widely explored but has involved indirect routes, including anodic dissolution of solid metal electrodes or the use of interfacial redox chemistry to generate base equivalents and drive MOF assembly. These methods are limited in scope, as the former relies on the use of an anode consisting of the metal ion to be incorporated into the MOF, and the latter relies on the compatibility of the metal/ligand solution with the probase that is subsequently oxidized or reduced. We report the facile, direct electrochemical syntheses of four iron-based MOFs via controlled potential oxidation of dissolved metal cations. Oxidation of Fe(II) at +0.75 V (vs Ag/Ag+) in a solution containing 2,6-lutidine and terephthalic acid affords highly crystalline Fe-MIL-101. Controlled potential electrolysis with carboxy-functionalized ITO affords Fe-MIL-101 grown directly on the surface of modified electrodes. The methods we report herein represent the first general routes that employ interfacial electrochemistry to alter the oxidation state of metal ions dissolved in solution to directly trigger MOF formation. The reported method is functional group tolerant and will be broadly applicable to the bulk synthesis or surface growth of a range of MOFs based on metal ions with accessible oxidation states.
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Project description:We demonstrate a nanostructure layer made of Ni80Fe20 (permalloy:Py) thin film conjugated MoS2 nano-flakes. Layers are made based on a single-step co-deposition of Py and MoS2 from a single solution where ionic Ni and Fe and MoS2 flakes co-exist. Synthesized thin films with MoS2 flakes show increasing coercivity and enhancement in magneto-optical Kerr effect. Ferromagnetic resonance linewidth as well as the damping parameter increaseed significantly compared to that of the Py layer due to the presence of MoS2. Raman spectroscopy and elemental mapping is used to show the quality of MoS2 within the Py thin film. Our synthesis method promises new opportunities for electrochemical production of functional spintronic-based devices.
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Project description:Compositing nanoparticles photo-catalyst with enormous surface areas metal-organic framework (MOF) will greatly improve photocatalytic performances. Herein, WO3 nanoparticles are partly embedded into pores of MIL-101 or only supported on the outside of representative MIL-101, which were defined as embedded structure WO3@MIL-101@WO3 and coating structure WO3&MIL-101 respectively. Different pH, concentration and loading percentage were researched. XRD, TEM and BET were carried to analyze the composites. Compared with the pristine WO3, all WO3 loaded MOF nanocomposites exhibited remarkable enhancing for the efficiency of photocatalytic degradation methylene blue under visible light. Their activity of the same loading percentage WO3 in embedded structure and coating structure have increased for 9 and 3 times respectively compared with pure WO3. The WO3@MIL-101@WO3 has 3 times higher efficiency than WO3&MIL-101, because the shorter electron-transport distance can make a contribution to electron-hole separation. The further mechanism involved has been investigated by radical quantify experiment, XPS and photoluminescence spectroscopy.
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Project description:MIL-101-NH2(Fe) is one of the effective photocatalytic metal-organic frameworks (MOFs) working under visible light. However, its powder-type form inhibits reusability in practical applications. In this study, we immobilized MIL-101-NH2(Fe) on a polymeric microfiber mesh to improve reusability while minimizing the loss of catalytic performance. To overcome the lack of surface functionality of the nylon fibers, an atomic layer deposition Al2O3 layer and NH2-BDC linker were introduced to facilitate uniform coating of the MOF on the fiber surface. The reactions of the metal precursor to the nylon substrate and NH2-BDC ligand of the MOF allow chemical bonding from the core to the shell of the entire hybrid catalytic materials. The resulting fiber-immobilized MOFs (Nylon@Al2O3@MOF) demonstrated high photocatalytic performance in the removal of RhB and Cr(VI) as representatives of organic dyes and heavy metals, respectively, while retaining over 85% of its efficiency after five cycles.
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Project description:In this work, we present the preparation of a hybrid material constituted by a Metal-Organic Framework (type MIL-101(Fe)) and a natural clay ceramic monolith (NCCM), the materials were successfully assembled through an in-situ hydrothermal method. The composites were characterized by powder X-ray diffraction (PXRD), thermogravimetric analysis (TGA), Fourier-transform infrared spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), N2 adsorption-desorption isotherms at 77 K and CO2 adsorption at 273 K; these techniques confirmed the obtaining of the hybrid material and, in addition, through studies before and after adsorption mechanisms involved were identified. Then, the As(V) adsorption capacity of the materials was evaluated using an aqueous arsenic solution; from which high adsorption capacities of up to 268 mg g- 1 and 61.5 mg g- 1, respectively. In addition, kinetic and equilibrium studies of As(V) adsorption were carried out. Finally, the potential capacities of the hybrid material consisting of Al2O3, AlO6-SiO4 and Fe3O4 for the adsorption of H3AsO4, were studied through density functional theory calculations.
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Project description:Three adsorbents based on the metal-organic frameworks (MOFs), viz.; MIL-88(Fe), NH2-MIL-88(Fe), and mixed-MIL-88(Fe) were synthesized using a microwave-assisted solvothermal technique. The as-synthesized MOFs were characterized by X-ray diffraction (XRD), Brunauer-Emmett-Teller (BET), field emission scanning microscopy (FESEM), X-ray photoelectron spectroscopy (XPS), thermogravimetric analysis (TGA), and Fourier transform infrared spectroscopy (FTIR). The MOFs were shown to possess highly crystalline and porous structures with specific surface areas of 1240, 941, and 1025 m2 g-1 and pore volumes of 0.7, 0.6 and 0.6 m3 g-1 for MIL-88(Fe), NH2-MIL-88(Fe) and mixed-MIL-88(Fe), respectively. Faster removal of a model polycyclic aromatic hydrocarbon, anthracene (ANT) within 25 minutes, was achieved when these MOFs were used as adsorbents in water. The removal efficiency was 98.3, 92.4 and 95.8% for MIL-88(Fe), NH2-MIL-88(Fe) and mixed-MIL-88(Fe), respectively. The kinetics and isotherms of the process were best statistically described by pseudo-second-order and Langmuir models, respectively, while the thermodynamic studies revealed the exothermic and spontaneous nature of the process. Docking simulations were found to be consistent with the experimental results with MIL-88(Fe) showing the best binding capacity with the ANT molecule.
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Project description:Tetracycline's accumulation in the environment poses threats to human health and the ecological balance, necessitating efficient and rapid removal methods. Novel porous metal-organic framework (MOF) materials have garnered significant attention in academia due to their distinctive characteristics. This paper focuses on studying the adsorption and removal performance of amino-modified MIL-101(Fe) materials towards tetracycline, along with their adsorption mechanisms. The main research objectives and conclusions are as follows: (1) NH2-MIL-101(Fe) MOF materials were successfully synthesized via the solvothermal method, confirmed through various characterization techniques including XRD, FT-IR, SEM, EDS, XPS, BET, and TGA. (2) NH2-MIL-101(Fe) exhibited a 40% enhancement in tetracycline adsorption performance compared to MIL-101(Fe), primarily through chemical adsorption following pseudo-second-order kinetics. The adsorption process conformed well to Freundlich isotherm models, indicating multilayer and heterogeneous adsorption characteristics. Thermodynamic analysis revealed the adsorption process as a spontaneous endothermic reaction. (3) An increased adsorbent dosage and temperature correspondingly improved NH2-MIL-101(Fe)'s adsorption efficiency, with optimal performance observed under neutral pH conditions. These findings provide new strategies for the effective removal of tetracycline from the environment, thus holding significant implications for environmental protection.
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Project description:The water contamination from pharmaceuticals and personal care products (PPCPs) has attracted worldwide attention in recent years because of its threat to public health. Berberine is a typical anti-inflammatory medicine and berberine wastewater is difficult to be treated due to its high toxicity, poor biodegradability, and high acidity. Metal-organic frameworks would be a good choice to remove berberine from wastewater due to its advantages of high specific surface area, ultrahigh porosity, and structural and functional tunability. In this study, MIL-101(Fe) was synthesized and used for the removal of berberine from water. Experimental results indicated that MIL-101(Fe) showed promising characteristics when berberine was adsorbed in acidic wastewater. The high concentration of chloride in berberine wastewater could promote the adsorption of berberine by MIL-101(Fe). Fitting of batch equilibrium data showed that MIL-101(Fe) had a maximum adsorption capacity of 163.93 mg/g for berberine removal at pH 7, and the berberine sorption on MIL-101(Fe) followed the pseudo-second-order model. Furthermore, the associate mechanism for berberine removal was proposed by characterizing the material and theoretical calculation. The X-ray power diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), and X-ray photoelectron spectroscopy (XPS) analysis showed that no chemical reaction occurred during the adsorption of berberine by MIL-101(Fe). Also, the theoretical calculation results indicated that π-π interactions may play the main role in the adsorption of berberine onto MIL-101(Fe). The findings of this study suggest that MIL-101(Fe) is a promising sorbent for berberine removal from wastewater.
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Project description:As an azo dye, OG has toxic and harmful effects on ecosystems. Therefore, there is an urgent need to develop a green, environmentally friendly, and efficient catalyst to activate peroxymonosulfate (PMS) for the degradation of OG. In this study, the catalysts MIL-101(Fe) and NH2-MIL-101(Fe) were prepared using a solvothermal method to carry out degradation experiments. They were characterized by means of XRD, SEM, XPS, and FT-IR, and the results showed that the catalysts were successfully prepared. Then, a catalyst/PMS system was constructed, and the effects of different reaction systems, initial pH, temperature, catalyst dosing, PMS concentration, and the anion effect on the degradation of OG were investigated. Under specific conditions (100 mL OG solution with a concentration of 50 mg/L, pH = 7.3, temperature = 25 °C, 1 mL PMS solution with a concentration of 100 mmol/L, and a catalyst dosage of 0.02 g), the degradation of OG with MIL-101(Fe) was only 36.6% within 60 min; as a comparison, NH2-MIL-101(Fe) could reach up to 97.9%, with a reaction constant k value of 0.07245 min-1. The NH2-MIL-101 (Fe)/PMS reaction system was able to achieve efficient degradation of OG at different pH values (pH = 3~9). The degradation mechanism was analyzed using free-radical quenching tests. The free-radical quenching tests showed that SO4•-, •OH, and 1O2 were the main active species during the degradation of OG.
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Project description:Nanomaterial technology has attracted much attention because of its antibacterial and drug delivery properties, among other applications. Metal-organic frameworks (MOFs) have advantages, such as their pore structure, large specific surface area, open metal sites, and chemical stability, over other nanomaterials, enabling better drug encapsulation and adsorption. In two examples, we used the common pathogenic bacterium Staphylococcus aureus and highly infectious influenza A virus. A novel complex MIL-101(Fe)-T705 was formed by synthesizing MOF material MIL-101(Fe) with the drug favipiravir (T-705), and a hot solvent synthesis method was applied to investigate the in vitro antibacterial and antiviral activities. The results showed that MIL-101(Fe)-T705 combined the advantages of nanomaterials and drugs and could inhibit the growth of Staphylococcus aureus at a concentration of 0.0032 g/mL. Regarding the inhibition of influenza A virus, MIL-101(Fe)-T705 showed good biosafety at 12, 24, 48, and 72 h in addition to a good antiviral effect at concentrations of 0.1, 0.2, 0.4, 0.8, 1.6, and 3 μg/mL, which were higher than MIL-101(Fe) and T-705.
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